From liquid to solid: A novel approach for utilizing sulfate reduction effluent through phase transition - Effluent-induced nanoscale zerovalent iron sulfidation.

This study investigated the use of sulfate reduction effluent (SR-effluent) to induce sulfidation on nanoscale zerovalent iron (nZVI). SR-effluent-modified nZVI achieved a 100% improvement in Cr(VI) removal from simulated groundwater, a result comparable to cases where other, more typical sulfur precursors (Na2S2O4, Na2S2O3, Na2S, K2S6, and S0) were used. Through a structural equation model analysis, amendment of nanoparticles' agglomeration (standardized path coefficient (std. path coeff.) = -0.449, p < 0.05) and hydrophobicity (std. path coeff. = 0.100, p < 0.05) and direct reaction between iron-sulfur compounds and Cr(VI) (std. path coeff. ranged from -0.195 to 0.322, p < 0.05) were primarily contributing to sulfidation-induced Cr(VI) removal enhancement. Regarding the property improvement of nZVI, the SR-effluent's corrosion radius played a crucial role in tuning the content and distribution of the iron-sulfur compounds based on the core-shell structure of the nZVI and the redox processes at the aqueous-solid interface.