New Outcomes of Beryllium Chemistry: Lewis Base Adducts for Salt Elimination Reactions.

A range of mono- and bis-adducts of beryllium dichloride with cyclic (alkyl)(amino)carbenes (CAAC), cyclic diamidocarbene (DAC), and carbodiphosphorane (CDP) are prepared, and their reactions with nucleophiles are studied. Salt elimination with Yamashita and Nozaki's lithium diazaborolide reagent led to the isolation of an unsymmetrical beryllium diazaborolyl complex and a base-stabilized diazaborolyl beryllium chloride. From structural and spectroscopic analyses, the Be-B bonding in these compounds was determined to be polar covalent in character. In addition, the nucleophilic addition of magnesium anthracenediyl to one of the adducts resulted in the isolation of an interesting tetracyclic beryllium-bridged molecule.