Degradation of trichloroethylene by graphene-supported trace amounts of microscale zero-valent iron: The role of electrochemistry.

Dechlorination of chlorinated pollutants is an important means to reduce the toxicity, persistence and bioaccumulation of pollutants. Relevant to this matter, the utilization of microscale zero-valent iron (mZVI) shows great potential. However, the passivation of Fe0 presents challenges, resulting in slow dechlorination, dangerous accumulation of incomplete dechlorination intermediates, and susceptibility to corrosion. To solve this problem, we introduced graphene (GO) to modify mZVI. The results showed that mZVI-GO (99% removal rate) could significantly increase the dechlorination capacity of trichloroethylene (TCE) compared to sole mZVI (30% removal rate), with approximately three times the performance of mZVI. The final products are ethylene and ethane with peak concentrations of around 70% and 30%, respectively. Importantly, the final system avoids toxic by-products. At the same time, after four cycles of mZVI-GO experiment, the removal effect of TCE can reach 85%, indicating that it has good recyclability. In corrosion tests, mZVI-GO is more corrosion-resistant than mZVI. The addition of GO during dechlorination diminishes the corrosion potential of mZVI, elevates its electron transfer capacity and reactivity, and enables more direct electron transfer to facilitate TCE degradation. Additionally, the improved electrochemical properties also facilitate the interaction between mZVI and water, leading to the continual generation of H∗, and creates a synergistic effect between GO and mZVI, thereby accelerating the dechlorination of TCE. This study elucidated the pivotal role of electrochemical properties in facilitating the reduction and dechlorination of TCE, thereby providing a novel approach for achieving profound TCE dechlorination.