Geochemistry of arsenic in soils with a focus on calcareous soils: control strategies and perspectives.

Arsenic (As) contamination has become a significant environmental challenge due to the global expansion of industrial, agricultural, and mining activities, which contribute to the contamination of water, air, soils, and biota with As and other metals and metalloids. This review elucidates the geochemical behavior of As in soils, focusing on the factors influencing its dynamics and the effectiveness of various remediation techniques, particularly in calcareous soils. Calcareous soils, characterized by their unique properties, exhibit intricate interactions with As, necessitating a deeper understanding of the mechanisms driving these processes. Compared to other soil types, the bioavailability of As in calcareous soils is generally lower, largely due to their elevated pH and the presence of calcium carbonate (CaCO3). These factors contribute to the enhanced adsorption of As by soil organic and mineral components, forming less soluble As-CaCO3 complexes and decreasing As solubility. Despite this, research on As geochemistry in calcareous soils and the development of effective removal techniques still needs to be completed, emphasizing the need for further study. Additionally, this review explores future research directions in the context of As contamination and remediation, integrating case studies and advanced technologies to highlight innovative approaches for mitigating As contamination in calcareous soils.