Hyphenated liquid electrode glow discharge-dielectric barrier discharge molecular emission spectrometry for determination of dithiocarbamates.

A hyphenated liquid electrode glow discharge (LEGD)-dielectric barrier discharge (DBD) molecular emission spectrometer was constructed and used as a novel liquid chromatography (LC) detector for dithiocarbamates (DTC) determination. The LEGD was used as an acidolysis reactor for the in-situ transformation of DTCs into CS2 with high efficiencies of 74.11-97.98%. The DBD was used to excite CS2 gas to generate a specific molecular emission at 257.94 nm. The linear correlation coefficient of the method was > 0.99 from 1 to 200 μg mL-1. The detection limits ranged from 0.1 to 0.3 μg mL-1 with 76-119% recovery and relative standard deviations of 0.2-8.5%. Moreover, the hyphenated microplasma spectrometer achieved low power consumption, low temperature, immediate acidolysis, and high transformational efficiency, and can detect each DTC when combined with LC.