Surface-modified silicalite-1-filled PDMS membranes for pervaporation dehydration of trichloroethylene.

In this study, the impact of silane coupling agents, namely 3-aminopropyltrimethoxysilane (APTMS), trimethylchlorosilane (TMCS), and 1,1,3,3-tetramethyldisilazane (TMDS), on the hydrophobicity of silicalite-1 zeolite was investigated to enhance the pervaporation separation performance of mixed matrix membranes (MMMs) for trichloroethylene (TCE). The hydrophobicity of TMCS@silicalite-1 and TMDS@silicalite-1 particles exhibited significant improvement, as evidenced by the increase in water contact angle from 96.1° to 101.9° and 109.1°, respectively. Conversely, the water contact angle of APTMS@silicalite-1 particles decreased to 85.2°. Silane-modified silicalite-1 particles were incorporated into polydimethylsiloxane (PDMS) to prepare mixed matrix membranes (MMMs), resulting in a significant enhancement in the adsorption selectivity of trichloroethylene (TCE) on membranes containing TMCS@silicalite-1 and TMDS@silicalite-1 particles. The experimental findings demonstrated that the PDMS membrane with a TMDS@silicalite-1 particle loading of 40 wt% exhibited the most favorable pervaporation performance. Under the conditions of a temperature of 30 °C, a flow rate of 100 mL min-1, and a vacuum degree of 30 kPa, the separation factor and total flux of a 3 × 10-7 wt% TCE aqueous solution were found to be 139 and 242 g m-2 h-1, respectively. In comparison to the unmodified silicalite-1/PDMS, the separation factor exhibited a 44% increase, while the TCE flux increased by 16%. Similarly, when compared to the pure PDMS membrane, the separation factor showed an 83% increase, and the TCE flux increased by 20%. These findings provide evidence that the hydrophobic modification of inorganic fillers can significantly enhance the separation performance of PDMS membranes for TCE.