Electrochemical degradation of toluene-2,4-diamine by graphene oxide-modified Ti/Sb-SnO2/α-PbO2/β-PbO2 anode: Performance and mechanism.

The formidable toluene-2,4-diamine (TDA), a potential human carcinogenic pollutant, environmental challenge necessitates investigating an efficient technology and clarifying its removal mechanism. Accordingly, we prepared a graphene oxide-modified PbO2 anode (Ti/Sb-SnO2/α-PbO2/GO-β-PbO2) to degrade TDA using electrochemical oxidation technology given its high oxidation capacity and green feature. The Ti/Sb-SnO2/α-PbO2/GO-β-PbO2 attained 100 % TDA and 82.7 % COD removal efficiency after 3.0 h electrolysis for its high oxygen evolution overpotential (2.08 V vs.SCE), superior ⋅OH generation capacity, and hydrophobic surface (121.2°). The quenching experiments and EPR tests all confirmed the vital role of both ⋅OH and SO4·-, resulting in the oxidation of the benzene ring and amino group. Moreover, the (Ti/Sb-SnO2/α-PbO2/GO-β-PbO2 also presented an improved stability with the accelerated lifetime prolonged by about 50.8 %. Therefore, this work provides a toolbox for treating TDA wastewater and a good reference for fabricating PbO2 anode via a facile yet effective method.