High-Flow-Rate Trace Formaldehyde Detection Based on Ultraviolet Photoacoustic Spectroscopy Using a Long Resonant Photoacoustic Cell.

Formaldehyde (H2CO) is a hazardous volatile organic compound widely present in indoor and industrial environments, and its real-time, highly sensitive detection is essential for environmental safety. However, existing detection techniques often face challenges in simultaneously achieving high sensitivity and long-term stability, and many conventional photoacoustic spectroscopy (PAS) systems rely strongly on low gas flow rates to suppress flow-induced noise, which limits their applicability for continuous online monitoring. In this work, an ultraviolet photoacoustic spectroscopy (UV-PAS)-based H2CO detection system operating in a nitrogen (N2) background is developed. The system integrates a compact differential photoacoustic cell (PAC) with a 320 nm ultraviolet laser source, in which the resonator length and buffer configuration are carefully optimized to enhance acoustic resonance and effectively suppress flow-related disturbances. Notably, a key innovation of this study is that the system maintains a stable photoacoustic response even under relatively high gas flow conditions. Experimental results demonstrate that at a flow rate of 250 sccm, the photoacoustic signal amplitude remains stable, and the noise level is well controlled, significantly reducing the dependence of conventional PAS systems on low-flow operation. The photoacoustic cell exhibits a resonant frequency of 1767 Hz and a quality factor of 46. Calibration using a 47.31 ppm H2CO:N2 gas mixture shows a good linear response with a correlation coefficient of R2 = 0.98844. The minimum detection limit reaches 2.50 ppm at a 1 s integration time and is further improved to 88.1 ppb at an integration time of 2202 s based on Allan-Werle deviation analysis. These results demonstrate that the proposed UV-PAS system provides a sensitive, stable, and cost-effective solution for real-time trace H2CO detection while retaining robust performance at elevated gas flow rates, highlighting its strong potential for practical applications.