Tailoring PLA-Based Composite Membranes with Ionic Liquids for Efficient H2/CO2 Separation in Reforming Processes.

Hydrogen (H2), produced from syngas and the Water-Gas Shift reaction, plays a vital role as both an energy carrier and an essential industrial feedstock. This preliminary study examines the effect of incorporating ionic liquids into PLA membranes for the separation of hydrogen (H2) from carbon dioxide (CO2), aiming to provide a more energy-efficient alternative to the conventional Pressure Swing Adsorption process. Specifically, neat PLA and composite membranes containing cholinium-based ionic liquids at concentrations of 3% and 10% were fabricated. Their thermal properties and microstructural characteristics were systematically analyzed, alongside their gas separation performance. The most promising membrane was further evaluated under humid conditions to assess the impact of water presence. The PLA membrane incorporating 3% cholinium glycinate ionic liquid demonstrated the best performance, achieving a hydrogen permeability of 111 Barrer and an H2/CO2 selectivity of 8.2, surpassing the Robeson Upper Bound reported in 2008. However, the presence of water led to a decline in separation performance, indicating that effective water removal is necessary prior to membrane application in hydrogen purification.