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Physical chemistry chemical physics : PCCP · 2025

Reply to the 'Comment on "Unravelling the kinetics, isotherms, thermodynamics, and mass transfer behaviours of Zeolite Socony Mobil - 5 in removing hydrogen sulphide resulting from a dark fermentative biohydrogen production process"' by K. H. Chu, M. A. Hashim and M. Hafiz Zawawi, Phys. Chem. Chem. Phys., 2025, 27, DOI: 10.1039/D4CP04682J.

КомментарийСтатьяНазвание и аннотация: Перевод в очереди
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Asman Muhammad Khairul Adha, Lutpi Nabilah Aminah, Wong Yee-Shian, Ong Soon-An, Hanif Muhammad Adli, Ibrahim Naimah, Dahalan Farrah Aini, Taweepreda Wirach, Nazri Raja Nazrul Hakim Raja

Аннотация

In this reply, we address the concerns raised regarding the theoretical consistency of the modeling approaches used in our original study on hydrogen sulfide adsorption onto ZSM-5. Specifically, the issues relate to the application of the Temkin isotherm, the Weber-Morris intraparticle diffusion model, and the use of a dimensional distribution coefficient in the thermodynamic analysis. We acknowledge that the simplified Temkin model was misapplied and does not strictly conform to theoretical requirements; however, it was used to represent mid-range adsorption behavior consistent with our experimental conditions. The inclusion of an intercept in the Weber-Morris model is defended as a diagnostic feature that reveals the contribution of boundary layer resistance, which is relevant in fixed-bed gas-solid systems. The use of a dimensional coefficient Kd = qe/Ce in thermodynamic calculations is justified based on its practicality in real gas-phase systems where activity-based constants are not easily defined. Collectively, while theoretical refinements are acknowledged, the main findings of the original study remain robust and well-supported by the experimental evidence. In addition, the opportunities for further refinement in isotherm fitting and thermodynamic calculations are acknowledged, and directions for future work are outlined.

Предметные рубрики MeSH

ИП Урсолов Владлен Сергеевич

ИНН 500118482352 · ОГРНИП 314500117700049

Реквизиты и контакты