One-Step Electrospun WO3/CuO p-n Heterojunction Nanocomposites for Ultrasensitive and Rapid H2S Detection.

Hydrogen sulfide (H2S), a critical industrial gas, exhibits high toxicity, flammability, and strong corrosiveness, posing severe health risks at elevated concentrations. Consequently, developing highly sensitive and rapid-response detection methods is imperative. In this study, WO3/CuO nanocomposites were synthesized via a one-step electrospinning technique, enabling the fabrication of high-performance H2S gas sensors. The gas-sensing properties of WO3/CuO nanocomposites for H2S detection were systematically investigated. The composite sensor demonstrated optimal performance at 150 °C, with a CuO mass fraction of 5 wt % yielding the highest H2S response. For 5 ppm of H2S in air, the WO3/CuO sensor exhibited a response value of 68.43%, with a rapid response time of 24 s and recovery time of 78 s at 150 °C. The enhanced H2S sensing performance is attributed to the formation of p-n heterojunctions at the WO3/CuO interface, which improves long-term stability. This mechanism was corroborated by in situ TEM and XRD analyses. Furthermore, the unique interaction between CuO and H2S enhances low-concentration detection sensitivity. First-principles calculations revealed that the performance improvement arises from CuO sensitization effects and heterojunction formation. These findings provide novel insights and a theoretical foundation for advancing high-reliability gas sensor technologies.