Nitrogenous Intermediates in NOx-involved Electrocatalytic Reactions.

Chemical manufacturing utilizing renewable sources and energy emerges as a promising path towards sustainability and carbon neutrality. The electrocatalytic reactions involving nitrogen oxides (NOx) offered a potential strategy for synthesizing various nitrogenous chemicals. However, it is currently hindered by low selectivity/efficiency and limited reaction pathways, mainly due to the difficulties in controllable generation and utilization of nitrogenous intermediates. In this minireview, focusing on nitrogenous intermediates in NOx-involved electrocatalytic reactions, we discuss newly developed methodologies for studying and controlling the generation, conversion, and utilizing of nitrogenous intermediates, which enable recent developments in NOx-involved electrocatalytic reactions that yield various products, including ammonia (NH3), organonitrogen molecules, and nitrogenous compounds exhibiting unconventional oxidation states. Furthermore, we also make an outlook to highlight future directions in the emerging field of NOx-involved electrocatalytic reactions.