Thiol-decorated defective metal-organic framework for effective removal of mercury(II) ion.

Removal of mercury (Hg) ion from water is important while still faces challenges in capacity and adsorption speed. Herein, using thiol-containing mercaptoacetic acid (MA) as the template, we constructed a novel metal-organic framework (MOF) adsorbent, Zr-MSA-MA (MSA, mercaptosuccinic acid). Unlike other monodentate acids such as acetic acid and formic acid, MA benefits to maintain high-content binding sites, in the meantime of defect formation. On the basis, Zr-MSA-MA exhibits a high adsorption capacity of 714.8 mg g-1 for Hg2+ and fast adsorption kinetics, superior to other MOF-based adsorbents. Co-existing metal ions and pH have only slight interference for the adsorption behavior. Besides, the adsorption is proved to an endothermic reaction and the adsorbent can be regenerated based on a simple elution. Further analysis indicates the strong chemical bonding of Hg2+ and -SH is the main adsorption mechanism. Thus, our work demonstrates the Zr-MSA-MA can serve as a potential adsorbent for Hg2+, and provides a novel strategy to construct defective adsorbent via using active group-containing template.