Organophotoredox-Catalyzed Arylation and Aryl Sulfonylation of Morita-Baylis-Hillman Acetates with Diaryliodonium Reagents.

We report an organophotoredox-catalyzed stereoselective allylic arylation of MBH acetates with a palette of diaryliodonium triflates (DAIRs) to provide the corresponding trisubstituted alkenes in moderate to good yields. The method could be extended to three-component coupling involving 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct (DABSO) as a sulfur dioxide surrogate for the synthesis of biologically relevant allylic sulfones. Both of these reactions were carried out under mild conditions featuring broad scope, robustness, and appreciable functional group tolerance.