Liquid Metal-Based Route for Synthesizing and Tuning Gas-Sensing Elements.

There is a strong demand for developing tunable and facile routes for synthesizing gas-sensitive semiconducting compounds. The concept of synthesizing micro- and nanoparticles of metallic compounds in a tunable process, which relies on liquid metals, is presented here. This is a liquid-based ultrasonication procedure within which additional metallic elements (In, Sn, and Zn) are incorporated into liquid Ga that is sonicated in a secondary solvent. We investigate liquid metal sonication in dimethyl sulfoxide (DMSO) and water to show their impact on the size, morphology, and crystal structure of the particulated products. The synthesized materials are annealed to investigate their responses to model reducing (H2) and oxidizing (NO2) gas species. The preparation process in DMSO gives rise to predominantly monoclinic Ga2O3 crystals which are favorable for gas sensing, while the emergence of rhombohedral Ga2O3 phases from the water sonication process led to inactive samples. The ease of tunability without hazardous precursors during the synthesis procedure is demonstrated. The route presented here can be uniquely employed for designing and engineering on-demand functional materials for sensing applications.