Formulation of ferric/phosphorus composite coating on coal gangue as a novel fertilizer for enhancing slow-release of silicon and implication of As, Cr and Pb.

Owing to the abundant silicon content in coal gangue, its conversion into fertilizer can help address large-scale storage. Nonetheless, the rapid release of silicon in coal gangue poses challenges for plants to fully utilize it. A slow-release fertilizer prepared by ferric/phosphorus composite coating on coal gangue (C@SP) was developed in the study. The findings revealed that the C@SP can facilitate slow release of Si and enhance the stabilization of As, Pb, and Cr in soil. C@SP can react with As and Cr to form stable Fe-As-PO4 and Fe-Cr-PO4 compounds. The -OH in C@SP can combine with Pb, transforming it into insoluble Pb, which was then integrated into the crystal structure with ferric/phosphorus composite or Fe(III)-oxyhydroxysulfate to create a more stable form. The silicon release was promoted by the conversion of the passivation film to iron oxides. Thus, the fertilizer holds promise for application in environmental activities.