Fabrication and Performance Enhancement of Wood Liquefaction-Based Carbon Fibers Modified with Alumina Nanoparticles.

In this paper, alumina-modified wood liquefaction (AL-WP) was prepared by blending nano-alumina (Al2O3) into wood liquefaction phenolic resin (WP) using a co-blending method. Alumina-modified wood liquefaction protofilament fiber (AL-WPF) was obtained by melt-spinning, curing, and thermo-curing processes, which were followed by carbonization to obtain alumina-modified wood liquefaction carbon fiber (AL-WCF). This paper focuses on the enhancement effect of nano-alumina doping on the mechanical properties and heat resistance of wood liquefaction carbon fiber (WCF), explores the evolution of graphite microcrystalline structure during the high-temperature carbonization process, and optimizes the curing conditions of AL-WPF. The results showed that the introduction of Al2O3 significantly improved the mechanical properties and heat resistance of carbon fibers. When 1.5% Al2O3 was doped and carbonized at 1000 °C, the tensile strength of AL-WCF was increased from 33.78 MPa to 95.74 MPa, there was an enhancement of 183%, its residual carbon rate could reach 79.2%, which was better than that of the undoped wood liquefaction (WCF), and it exhibited a more substantial heat-resistant property. In addition, the best curing process for alumina nanoparticle wood liquefiers was obtained by optimizing the curing conditions: hydrochloric acid concentration of 16%, formaldehyde concentration of 18.5%, temperature increase rate of 15 °C/min, holding time of 3 h, and holding temperature of 100 °C. These studies provide a theoretical basis and technical support for developing and applying carbon fibers from alumina-modified wood liquefiers.