Wei sheng yan jiu = Journal of hygiene research · 2025
[Determination of bisphenol A, nonylphenol, and octylphenol in PM_(2.5) by ultra-high performance liquid chromatography-tandem mass spectrometry].
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Liu Feng, Tang Binbin, Kang Yanhui, He Min
Аннотация
OBJECTIVE: To establish a method for determination of bisphenol A, nonylphenol, and octylphenol in fine particulate matter(PM_(2.5)) by ultra-high performance liquid chromatography tandem mass spectrometry.
METHODS: PM_(2.5 )was collected by quartz fiber filter membrane(90 mm), 1/8 of which was extracted by methanol and purified by octadecyl silane bonded silica gel(C_(18)). The compounds were separated by Waters BEH C_(18) column(2.1 mm×100 mm, 1.7 μ m) under the mobile phase consisted of 0.1% ammonia and methanol, and then detected by multi reaction monitoring scanning mode with ESI negative scan, and quantified by internal standard method.
RESULTS: The correlation coefficients(r) of the three compounds were more than 0.999 in the range of 0.05-50 ng/mL. The detection limit and quantification limit of the method were 0.0007-0.001 ng/m~3 and 0.003-0.005 ng/m~3, respectively. The recoveries of blank sample spiked with 0.1, 1.0 and 10.0 ng/mL standard substance were 91.7%-120.2%, with relative standard deviation of 4.2%-12.3%(n=6).
CONCLUSION: The method established is high sensitivity, rapid, and accuracy, which can be used for the monitoring of bisphenol A, nonylphenol, and octylphenol in PM_(2.5).
METHODS: PM_(2.5 )was collected by quartz fiber filter membrane(90 mm), 1/8 of which was extracted by methanol and purified by octadecyl silane bonded silica gel(C_(18)). The compounds were separated by Waters BEH C_(18) column(2.1 mm×100 mm, 1.7 μ m) under the mobile phase consisted of 0.1% ammonia and methanol, and then detected by multi reaction monitoring scanning mode with ESI negative scan, and quantified by internal standard method.
RESULTS: The correlation coefficients(r) of the three compounds were more than 0.999 in the range of 0.05-50 ng/mL. The detection limit and quantification limit of the method were 0.0007-0.001 ng/m~3 and 0.003-0.005 ng/m~3, respectively. The recoveries of blank sample spiked with 0.1, 1.0 and 10.0 ng/mL standard substance were 91.7%-120.2%, with relative standard deviation of 4.2%-12.3%(n=6).
CONCLUSION: The method established is high sensitivity, rapid, and accuracy, which can be used for the monitoring of bisphenol A, nonylphenol, and octylphenol in PM_(2.5).