Active metals decorated NiCo2O4 yolk-shell nanospheres as nanoreactors for catalytic reduction of nitroarenes and azo dyes.

Transition-metal oxides (TMOs) have received a great deal of research attention and have been widely used in a variety of fields. However, conventional TMOs do not possess high specific surface area, sufficient active site on their surfaces, and limited their applications in catalysis. This study presents a two-step method for synthesizing active metal (M) decorated NiCo2O4 (M/NiCo2O4, M = Pd or Cu) nanospheres with yolk-shell nanostructures. Taking advantage of the unique morphology and the combination of dual active components (i.e., active NiCo2O4 substrate and decorated active metal), the as-prepared M/NiCo2O4 yolk-shell nanospheres can be employed as nanoreactors in the organic reactions. In catalyzing the reduction of a representative nitroarene (i.e., 4-NP) by NaBH4, the Pd/NiCo2O4 nanoreactors exhibit a superior catalytic efficiency to their counterparts (Cu/NiCo2O4 and NiCo2O4). The turnover frequency is much higher than that of various TMOs supported nanocatalysts have been reported over the past five years. Furthermore, the Pd/NiCo2O4 nanoreactors show excellent stability and common applicability of the reduction of various substituted nitrobenzenes and azo dyes. This work provides new rational design concept and preparation strategy for efficient nanoreactors with dual active components and sheds light on the practical application of chemical reactions.