A novel dialdehyde cellulose-based colorimetric and turn-on fluorescent probe for H2S detection and its application in red wine.

Hydrogen sulfide (H2S) is considered one of the most important gaseous transmitters in the metabolic system, and the abnormal concentration of H2S is associated with a variety of diseases. Up to now, it is still a challenge to develop a portable assay for H2S even though the research about the detection of H2S is booming. Herein, a novel bifunctional dialdehyde-cellulose fluorescent probe DAC-DPD was prepared with high selectivity and sensitivity to H2S with colorimetric and fluorescent "turn-on" characteristics, and the limit of detection (LOD) of DAC-DPD for H2S was 0.831 μM. The sensing mechanism of DAC-DPD's to H2S was a Michael addition reaction confirmed by HRMS, 1H NMR and density-functional theory (DFT) calculations. DAC-DPD can be used to detect H2S in red wine samples. In Addition, the prepared DAC-DPD embedded fluorescent membrane can be used as a reliable sensing platform for rapid detection of H2S. It provided a convenient and rapid detection material, simplifying the detection process of H2S, which is of great significance for the development of cellulose-based fluorescent smart material.