Enhanced nutrient control efficiency in sediments using modified clay inactivation coupled with aquatic vegetation in the confluence area of a eutrophic lake.

Developing a long-term method for controlling sediment N and P release is important for enabling lake restoration. In this study, inactivation methods using lanthanum-modified clay, modified zeolite, or planting aquatic vegetation and their combinations were used in the control internal sediment loading (pore water N and P concentrations and their fluxes), and the efficacies of the methods were analyzed. The results indicated that compared to the control sediment, the addition of P sorbent, which was La and Al co-modified attapulgite (ACLA), and N sorbent, which was NaCl-modified zeolite (modified zeolite), planting of aquatic vegetation Vallisneria spiralis (V. spiralis), and a combination of sorbents and plants effectively reduced the porewater nutrient content and its fluxes across the sediment-water interface. However, the reduction in pore water nutrients and flux were superior when using a combination of clay inactivation and aquatic planting. The poorest sediment N and P control was achieved by planting V. spiralis alone. The addition of La and Al co-modified attapulgite (ACLA) and modified zeolite efficiently reduced N and P in the sediment, but the N and P sorbents did not achieve long-lasting nutrient release control. The high efficiency obtained by the combination of modified clay-based inactivation and V. spiralis was likely due to the strong chemical sorption capacity of clay and oxygenation by the rhizosphere of aquatic vegetation. These results show that a combination of chemical and ecological methods would be the most effective approach to remediate polluted sediments in the long term.