Study on H2SO4-modified corn straw biochar as substrate material of constructed wetland.

The high value resource utilization of corn straw is a long-term problem at present and in the future. Biochar preparation is an important utilization way of corn straw. The research on city tail water treated by constructed wetland (CW) with biochar was carried out to further increase the wastewater treatment capacity of the CW. Surface characterization, structural characteristics, and adsorption of straw biochar modified by different acids were measured. The study found that the ability of H2SO4 to remove ash from biochar was stronger than other acids and H2SO4-biochar was easy to be cleaned without H2SO4 residue. The performance of biochar modified by H2SO4 was obviously better than other acids, and the biochar adsorption was enhanced. The modification of biochar substrate modified by H2SO4 in CW reduced the change of electrical conductivity (EC) and promoted denitrification. H2SO4-modified biochar promoted the absorption of N and P by Iris pseudacorus L. The compound modification effect of straw biochar was obvious. The results revealed the acid modification characteristics of straw biochar, which were beneficial for increasing the wastewater treatment rate by CW. This study will promote the sustainable development of CW.