Synthesis, optimization via response surface methodology, and structural properties of carboxymethylcellulose/curcumin/graphene oxide biocomposite films/coatings for the shelf-life extension of shrimp.

In this study, carboxymethylcellulose (CMC), curcumin (Cur), and graphene oxide (GO) were used to prepare a novel biocomposite film (CMC-Cur-GO). A central composite design under response surface methodology was employed to optimize the films in terms of water vapor permeability (WVP) and swelling percentage (SP). Under the optimum conditions, which the rates of CMC, GO and curcumin were found to be 1350 mg, 29.99 mg, and 0.302 g, respectively, WVP and SP of CMC-Cur-GO were obtained 0.902 × 10-8 (g/m·h·Pa) and 13.62 %, respectively. The biocomposite films (CMC, CMC-Cur, CMC-GO and CMC-Cur-GO) were characterized by Fourier transform infrared spectroscopy, field-emission scanning electron microscope, thermal gravimetric analysis, X-ray diffraction analysis, ultraviolet-vis light transmittance, moisture content, and mechanical properties. Compared with pure CMC film, the tensile strength, elongation at break and Young's modulus of CMC-Cur-GO were significantly improved by up to 75 %, 41 % and 23 %, respectively (p < 0.05). Then, CMC-Cur-GO was applied as a coating solution for the shrimps. The coated shrimps with the CMC-Cur-GO significantly (p < 0.05) showed a noteworthy improvement in microbial quality (total and psychrotrophic bacterial count), chemical deterioration and lipid oxidation (pH and total volatile basic nitrogen, peroxide value and thiobarbituric acid) and physical characteristic (weight loss) as compared to other samples. The CMC-Cur-GO coating could increase the shelf life of shrimp under refrigerated storage.