Effects of Mn(II) addition on Cd(II) removal by hydrated manganese dioxide.

In this study, the redox homogeneous precipitation method was applied to synthesize hydrated manganese dioxide (HMO) and to study the removal performance of Cd(II) from wastewater. Moreover, a small amount of Mn(II) could still combine with HMO without causing the desorption of Cd(II). A novel discovery was that the synergistic effect of KMnO4 and Mn(II) could directly regenerate MnO2 to deeply remove Cd(II), realizing the recycling of MnO2. The influence of Mn(II) addition on the adsorption behavior of Cd(II) was discussed in terms of pH, Mn(II) addition mode, initial concentration of Mn(II) or Cd(II), and contact time. The adsorption of Cd(II) on HMO could be better in line with the Langmuir model, while that of Mn(II) accorded with the Freundlich model. The pseudo-second-order kinetic fitting results indicated that the removal of Cd(II) and Mn(II) on HMO belonged to chemisorption. SEM, XRD, FTIR, and XPS analysis demonstrated that Cd(II) was trapped by forming an inner-sphere complex on HMO, and the added Mn(II) and KMnO4 could regenerate MnO2 through oxidation-reduction reaction, wrapping outside of Cd(II) for a purpose of deep removal of Cd(II). HIGHLIGHTS: 1)A small amount of Mn(II) can bind to HMO without causing Cd(II) desorption 2)A large amount of Mn(II) can cause partial desorption of Cd(II) 3)Large amount of Mn(II) will partially bind to the surface of HMO or Cd(II) complexes 4)Deeply remove Cd(II) without eluting and regenerating HMO.