Development of a 2D Network of Zinc Organophosphate with an 8-Membered Ring Core Having Corrosion Resistance Properties.

A 2D framework, i.e., zinc organophosphate [Zn(tmbiph)(solv)]2 (tmbiphH4 = tetramethyl-[1,1'-biphenyl]-4,4'-diyl bis(dihydrogen phosphate); solv = 2H2O) with an eight-membered ring core has been developed. The hierarchical and rational design of the zinc organophosphate has been achieved by carefully designing an organic bisphosphate ligand with two phosphate monoester groups connected through extended aromatic rings with methyl groups at ortho positions. The development of the 2D network does not require any ancillary ligand due to participating two phosphate groups in the coordination. The molecular structure of the zinc phosphate material was determined using single-crystal X-ray diffraction technique. The corresponding Co and Cu organophosphate materials have also been obtained using the same synthetic method; however, these compounds could not be confirmed structurally due to nondiffractive crystal quality. The structure of zinc organophosphate obtained through single-crystal X-ray diffraction has also been supported by theoretical calculations using density function theory. Furthermore, the zinc organophosphate material has been employed as an corrosion inhibitor for mild steel. The effect of the zinc phosphate framework on mild steel in 1 M HCl was investigated using polarization and electrochemical impedance spectroscopy. This study suggests that such phosphate inhibitors can be employed in the form of a thin protective layer on the electrode surface.