Advances of functional graphdiyne in separation and detection.

Separation and detection technologies are essential tools for ensuring quality, safety and efficiency across various industries. Graphdiyne (GDY), a carbon material made up of alkyne bonds conjugated with benzene rings to form a planar all-carbon network, is increasingly utilized in the fields of separation and detection. GDY is becoming an ideal separation medium due to its adjustable pore sizes, unique alkyne-rich framework, and easy to be functionalized. On the other hand, GDY shows great potential in detection with the advantages of efficient photoelectric effect, high carrier mobility, and large surface areas to provide active sites. This review summarizes the progress of functional GDY in separation and detection from 2011 to 2024. Various synthesis methods were introduced on improving the properties of GDY in separation and detection. Efforts have increasingly focused on the development of functional GDY in separation functionalities such as magnetic and membranous separations. Moreover, the application of functional GDY in detection technologies are discussed such as electrochemical, spectroanalysis, and dual-mode approaches. Finally, the promising research directions and prospects of functional GDY are discussed to explore further applications in both separation and detection.