Indium-Iron Oxide Nanosized Solid Solutions as Photocatalysts for the Degradation of Pollutants under Visible Radiation.

A series of solid solutions of indium and iron oxides with different In/Fe ratios (InxFeyO3, with x + y = 2) were synthesized in the form of nanoparticles (diameter of ca. 30-40 nm) with the purpose of generating enhanced photocatalysts with an intermediate band gap compared to those of the monometallic oxides, In2O3 and Fe2O3. The materials were prepared by co-precipitation from an aqueous solution of iron and indium nitrates and extensively characterized with a combination of techniques. XRD analysis proved the formation of the desired InxFeyO3 solid solutions for Fe content in the range 5-25 mol%. UV-Vis absorption analysis showed that the substitution of In with Fe in the crystalline structure led to the anticipated gradual decrease of the band gap values compared to In2O3. The obtained semiconductors were tested as photocatalysts for the degradation of model organic pollutants (phenol and methylene blue) in water. Among the InxFeyO3 solid solutions, In1.7Fe0.3O3 displayed the highest photocatalytic activity in the degradation of the selected probe molecules under UV and visible radiation. Remarkably, In1.7Fe0.3O3 showed a significantly enhanced activity under visible light compared to monometallic indium oxide and iron oxide, and to the benchmark TiO2 P25. This demonstrates that our strategy consisting in engineering the band gap by tuning the composition of InxFeyO3 solid solutions was successful in improving the photocatalytic performance under visible light. Additionally, In1.7Fe0.3O3 fully retained its photocatalytic activity upon reuse in four consecutive cycles.