Nonstoichiometric Doping of La0.9FexSn1-xO3 Hollow Microspheres for an Ultrasensitive Formaldehyde Sensor.

Oxygen vacancies play an essential role in gas-sensitive materials, but the intrinsic oxides are poorly controlled and contain low oxygen vacancy concentrations. In this work, we prepared La0.9Fe1-xSnxO3 microspheres with high sensitivity and controllability by a simple hydrothermal method, and then, we demonstrated that it has many oxygen ion defects by X-ray photoelectron spectroscopy and electron paramagnetic resonance characterization. The gas sensor exhibited ultrahigh response, specific recognition of formaldehyde gas, and excellent moisture resistance. By comparing the composites with different doping ratios, it was found that the highest catalytic activity was reached when x = 0.75, and the response value of La0.9Fe0.75Sn0.25O3 hollow microspheres at 200 °C reached 73-10 ppm of formaldehyde, which is 188% higher than that of intrinsic LaFeO3 hollow microspheres. On the one hand, due to the absence of A-site La3+ and the replacement of B-site Fe3+ by Sn4+, a large number of oxygen vacancies are induced on the surface and in the interior of the materials; on the other hand, it is also related to the large specific surface area and gas channels caused by the particular structure.