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DOI 10.1002/smll.202305126

Медицинская библиотека · Small (Weinheim an der Bergstrasse, Germany) · 2023

Unprecedented Multifunctionality in Novel Monophase Micro/Nanostructured Ti-Zn Alloy.

Vikraman Hajeesh Kumar, George Jeena, Reji Rence P, Kuppuswamy Guru Prasad, Sutar Sanjay D, Swami Anita, Ramamoorthy Sharmiladevi, Sundaramurthy Anandhakumar, Pramanik Sumit, Velappa Jayaraman Surya, Perumal Suresh, Sivalingam Yuvaraj, Mangalampalli S R N Kiran

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Аннотация

It is always challenging to integrate multiple functions into one material system. However, those materials/devices will address society's critical global challenges and technological demands if achieved with innovative design strategies and engineering. Here, one such material with a broader spectrum of desired properties appropriate for seven applications is identified and explored, and a glucose-sensing-triggered energy-storage mechanism is demonstrated. To date, the Titanium (Ti)-Zinc (Zn) binary alloys are investigated only as mixed phases and for a maximum of three applications. In contrast, the novel single phase of structurally stable 50 Ti-50 Zn (Ti0.5 Zn0.5 ) is synthesized and proven suitable for seven emerging applications. Interestingly, it is thermally stable up to 750 °C and possesses excellent mechanical, tribological properties and corrosion resistance. While exceptional biocompatibility is evident even up to a concentration of 500 µg mL-1 , the antibacterial activity against E. coli is also seen. Further, rapid detection and superior selectivity for glucose, along with supercabattery behavior, unambiguously demonstrate that this novel monophase is a remarkable multifunctional material than the existing mixed-phase Ti-Zn compounds. The coin-cell supercapacitor shows outstanding stability up to 30 000 cycles with >100% retention capacity. This allows us to prototype a glucose-sensing-triggered energy-storage-device system for wearable point-of-care diagnostic applications.

Для цитирования: Vikraman Hajeesh Kumar, George Jeena, Reji Rence P, Kuppuswamy Guru Prasad, Sutar Sanjay D, Swami Anita, Ramamoorthy Sharmiladevi, Sundaramurthy Anandhakumar, Pramanik Sumit, Velappa Jayaraman Surya, Perumal Suresh, Sivalingam Yuvaraj, Mangalampalli S R N Kiran. Unprecedented Multifunctionality in Novel Monophase Micro/Nanostructured Ti-Zn Alloy.. Small (Weinheim an der Bergstrasse, Germany). 2023. DOI: 10.1002/smll.202305126.
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