Phenolic acid-containing compounds enhanced Fe3+/peroxides processes for efficient removal of sulfamethoxazole in surface waters.

Sulfamethoxazole (SMX) in surface waters has raised widespread concerns due to its potential environmental and biological hazards. In this study, the performance, mechanism, and environmental application of phenolic acid-containing compounds (PACCs) enhanced Fe3+/peroxides processes for SMX degradation were investigated. PACCs with two Ar-OH groups exhibited the lowest toxicity and the best enhancement performance (65%-66% of PDS, 47%-58% of PMS and 61%-63% of H2O2), which were attributed to the excellent chelating and reducing ability towards Fe3+. Free radicals played the predominant role in PDS (37% of SO4-·, 34% of ·OH), PMS (37% of SO4-·, 35% of ·OH) and H2O2 (61% of ·OH) oxidation processes. FeIVO2+ play a non-negligible role in PDS and PMS processes (ŋ[PMSO2] = 52%-80% and ŋ[PMSO2] = 59%-72%). PDS and PMS processes were suitable for a pH range of 3.0-9.0, while the H2O2 process was 3.0-10.0. PDS and PMS processes exhibited stronger resistance to the common anions in surface waters. PMS process exhibited higher adaptability to surface waters quality (92%-98%). This study provides a novel approach for enhancing the degradation of SMX in natural surface waters.