Science (New York, N.Y.) · 2013
Galvanic replacement reactions in metal oxide nanocrystals.
СтатьяПоддержка исследования: вне правительства СШАНазвание и аннотация: Перевод в очереди
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Oh Myoung Hwan, Yu Taekyung, Yu Seung-Ho, Lim Byungkwon, Ko Kyung-Tae, Willinger Marc-Georg, Seo Dong-Hwa, Kim Byung Hyo, Cho Min Gee, Park Jae-Hoon, Kang Kisuk, Sung Yung-Eun, Pinna Nicola, Hyeon Taeghwan
Аннотация
Galvanic replacement reactions provide a simple and versatile route for producing hollow nanostructures with controllable pore structures and compositions. However, these reactions have previously been limited to the chemical transformation of metallic nanostructures. We demonstrated galvanic replacement reactions in metal oxide nanocrystals as well. When manganese oxide (Mn3O4) nanocrystals were reacted with iron(II) perchlorate, hollow box-shaped nanocrystals of Mn3O4/γ-Fe2O3 ("nanoboxes") were produced. These nanoboxes ultimately transformed into hollow cagelike nanocrystals of γ-Fe2O3 ("nanocages"). Because of their nonequilibrium compositions and hollow structures, these nanoboxes and nanocages exhibited good performance as anode materials for lithium ion batteries. The generality of this approach was demonstrated with other metal pairs, including Co3O4/SnO2 and Mn3O4/SnO2.