Rhodamine B functionalized luminescent metal-organic frameworks for ratiometric fluorescence sensing of hydroquinone.

The development of sensitive and selective detection methods for hydroquinone (HQ), a phenolic organic compound with high toxicity and low degradability, is of extraordinary importance. In this work, a fluorescent sensor based on functionalized luminescent metal-organic frameworks (LMOFs) was designed and applied for the ratiometric fluorescence sensing of HQ. The sensor was prepared by the functionalization of IRMOF-3 with rhodamine B (RhB), possessing dual-emission fluorescence properties. After the addition of HQ, the blue fluorescence of the IRMOF-3 framework was gradually weakened, while the red fluorescence of RhB remained unchanged, resulting in the continuous fluorescence change of RhB@IRMOF-3 with HQ concentrations. The sensing mechanism demonstrates that HQ changes the fluorescence of the sensor via electron transfer between benzoquinone and RhB@IRMOF-3. The RhB@IRMOF-3 sensor has the advantages of a wide linear range, quick response speed, and strong specificity for HQ detection. This work is the first attempt focusing on functionalized LMOFs for HQ fluorescence detection, which has superb potential for the application to real environmental water samples.