Catalytic Hydrogenation of CO2 by Direct Air Capture to Valuable C1 Products Using Homogenous Catalysts.

Growing atmospheric CO2 concentrations are a global concern and a primary factor contributing to global warming. Development of integrated CO2 capture and conversion protocols is necessary to mitigate this alarming challenge. Though CO2 hydrogenation to produce formic acid and methanol has seen many strides in the past decades, most studies utilize pure CO2 for this transformation. The CO2 concentration in the atmosphere stands at 400 ppm and reports that utilize direct air capture as the strategy to capture CO2 and utilize it for production of formic acid and methanol have only been reported in the past few years. This perspective summarizes such reports with a focus on the CO2-capturing additive, reaction solvent, and the molecular catalyst used to affect the transformation.