Heat and ZnCl2 chemical carbonization of date stone as an adsorbent: optimization of material fabrication parameters and adsorption studies.

In the present study, the optimization of factors for the fabrication of highly adsorptive activated carbon from agricultural waste (date stone) was investigated by using ZnCl2 as a chemical agent during the heat treatment. ZnCl2 acts as a dehydration agent during the heat treatment, allowing a better porosity. In addition, it boosts the fragmentation of the lignocellulosic structure and the condensation of carbon rings. The findings of this investigation showed that the synthesis conditions for better ZnCl2 chemical/heat carbonization to fabricate an adsorbent from date stone are 700 °C, 120 min, and 2.0 g/g. The characterization analysis showed that the as-prepared activated carbon exhibits a surface area of 1036 m2/g, an iodine number of 928.5 mg/g, and phenol number of 2.1 mmol/g, which are comparable to commercial activated carbons. Batch sorption tests to remove methylene blue (MB) from water showed a maximum adsorption capacity of 384.6 mg/g using the prepared activated carbon. Equilibrium data was best fitted by the Langmuir isotherm model. It was found also that the kinetic adsorption data obeyed the pseudo-first order, and both external diffusion and intra-particle diffusion control the adsorption. Based on the obtained results, the optimization of synthesis conditions may help the transfer of technology in terms of agriculture-based material valorization towards the environmental remediation.