Rapid optical sensor for recognition of explosive 2,4,6-TNP traces in water through fluorescent ZnSe quantum dots.

In this report, blue fluorescent zinc selenide quantum dots (ZnSe QDs) were synthesized using 3-mercaptopropionic acid through a direct aqueous route at a lower temperature of 70 °C. The photoluminescence (PL) characteristics of ZnSe QDs have been employed to recognize nitroaromatic compounds, i.e., traces of 2,4,6-TNP (picric acid) in water. The sensing of nitroaromatic compounds was performed via fluorescence techniques. The PL band of ZnSe QDs observed at 490 nm is selectively quenched with an increasing concentration of picric acid in DI water and river water. For the proposed sensing probe, the Stern-Volmer (S-V) plot shows linearity over the range of 2.0 µM-0.25 mM with the detection limit of 12.4 × 10-6 M without any interference effect of other nitroaromatic compounds. The plausible mechanism of PL quenching is considered as the inner filter effect, based on absorption, PL and PL lifetimes.