Transformation of CuS/ZnS nanomaterials to an efficient visible light photocatalyst by 'photosensitizer' graphene and the potential antimicrobial activities of the nanocomposites.

We report the growth of CuS/ZnS (CZS) nanoparticles (NPs) on the graphene sheet by a facile green synthesis process. The CuS/ZnS-graphene (CZSG) nanocomposites exhibit enhanced visible light photocatalytic activity towards organic dye (methylene blue) degradation than that of CZS nanoparticles. To find the reason for the enhanced photo-activity, we propose a new photocatalytic mechanism where graphene in the CZSG nanocomposites acts as a 'photosensitizer' for CZS nanoparticles. This distinctive photocatalytic mechanism is noticeably different from all other previous research works on semiconductor-graphene hybrid photocatalysts where graphene behaves as an electron reservoir to capture the electrons from photo-excited semiconductor. This novel idea of the photocatalytic mechanism in semiconductor-graphene photocatalysts could draw a new track in thinking for designing of graphene-based photocatalysts for solving environmental pollution problems and they also show remarkable antimicrobial activities.