Bidentate Donor-Functionalized N-Heterocyclic Carbenes: Valuable Ligands for Ruthenium-Catalyzed Transfer Hydrogenation.

Ruthenium complexes are by far the most studied compounds that catalyze hydrogen transfer reactions. In this review, we describe the use in this field of ruthenium complexes bearing bidentate donor-functionalized N-heterocyclic carbene ligands. The review specifically covers the application in transfer hydrogenations of (k2-CNHC,Y)-ruthenacyclic compounds where the Y donor atom is a N, P, O, or S atom, and where the N-heterocyclic carbene ligand is a classical imidazol-2-ylidene, a benzimidazol-2-ylidene, a mesoionic 1,2,3-triazolylidene, or an imidazol-4-ylidene ligand. Tridentate donor-functionalized N-heterocyclic carbene complexes thus fall outside the scope of the review. Applications in (asymmetric) transfer hydrogenation of ketones, aldehydes, imines, alkenes, and nitrobenzene are discussed.