Dialdehyde modified cellulose nanofibers enhanced the physical properties of decorative paper impregnated by aldehyde-free adhesive.

Impregnated decorative paper was an important wood-based panel finishing material. However, traditional impregnated decorative paper was impregnated with melamine-formaldehyde resin, which will release formaldehyde and harm the human health. To solve this problem, small molecule polyacrylate-polyethylene glycol (PEG) adhesive was used to achieve the non-formaldehyde addition of the impregnation system. The dialdehyde modified CNF (D-CNF), modified by sodium periodate (NaIO4), and triethylenediamine were introduced to enhance the surface properties of the impregnated decorative paper. The results showed that the incorporation of D-CNF and triethylenediamine imparted excellent physical strength and surface properties to impregnated decorative paper. When the dosage of 0.3 wt% D-CNF and 3 mL/100 g triethylenediamine in the compound emulsion, the hardness, abrasion resistant value and surface bonding strength of impregnated decorative paper adhered fiberboard reached 3H, 330 r of damage and 1.13 MPa, respectively. Thus, it could be effectively used for making high-performance formaldehyde-free impregnated decorative paper.