Recent Advances of Indium-Based Sulfides in Photocatalytic CO2 Reduction.

Urgent and significant, the mitigation of greenhouse effects and the preservation of the Earth's ecological environment are paramount concerns. Photocatalytic carbon dioxide (CO2) reduction technology holds immense promise as it directly harnesses renewable solar energy to convert CO2 into hydrocarbon fuels and valuable chemical products. Indium (In)-based sulfides have garnered significant attention in the realm of fundamental research on CO2 photocatalytic conversion. The photocatalytic performance exhibited by In-based materials is attributed to the appropriate bandgap (E g), unique electronic states, tunable atomic structure, and superior optoelectronic properties. Notably, In-based metal sulfides also show excellent potential for addressing challenges related to photocorrosion and carrier recombination. This paper highlighted the key structural features and commonly employed synthesis techniques of In-based metal sulfides. Furthermore, it summarized effective modification strategies aimed at optimizing the photocatalytic performance of these materials. A particular focus was placed on exploring the intricate structure-activity relationships, encompassing the influence of heterostructure construction, element doping, defect engineering, and co-catalyst modification on enhancing photocatalytic efficiency. Finally, the article identified the current challenges and outlined the promising future directions for In-based photocatalysts, hoping to provide valuable references for researchers.