Resonant Annihilation and Positron Bound States in Benzene.

Positrons attach to molecules in vibrationally resonant two-body collisions that result in greatly enhanced annihilation rates. Measurements of annihilation as a function of positron energy are presented for benzene using a cryogenic, trap-based beam. They establish a positron binding energy of 132±3  meV to test state-of-the-art theoretical calculations, and they exhibit many unexpected resonances, likely due to combination and overtone vibrational modes. The relationship of these results to the unique π-bonded structure of benzene is discussed.