Development of a Microwave Sensor for Real-Time Monitoring of a Micro Direct Methanol Fuel Cell.

Micro direct methanol fuel cells (μDMFCs) are a promising power source for microelectronic devices and systems. As the operating state and performance of a μDMFC is generally determined by both electrochemical polarization and methanol crossover, it is important to monitor the methanol concentration in μDMFCs. Here, we design and fabricate a microwave sensor and integrate it with a μDMFC for the online detection of methanol concentration in a nonintrusive way. The sensing area is set at the bottom of the anode chamber of a μDMFC which exhibits a maximum output power density of 28.8 mW cm-2 at 30 °C. With a square ring structure, the dual-mode microwave sensor shows a sensitivity of 9.5 MHz mol-1 L. Furthermore, the importance of methanol concentration monitoring is demonstrated in the long term. A relatively smooth methanol decline curve was obtained, which indicated a normal and stable operating status of the μDMFC. Derived from real-time recording data, fuel utilization was additionally calculated as 28.5%.