An overview in the development of cathode materials for the improvement in power generation of microbial fuel cells.

Since the high cost and low power generation hinder the overall practical application of microbial fuel cells (MFCs), numerous attempts have been made in the field of cathode materials to enhance the electrical performance of MFCs because they directly catalyze the oxygen reduction reactions (ORR). To choose a proper cathode material, following principles such as ORR activity, conductivity, cost-efficiency, durability, surface area, and accessibility should be taken into consideration. In preparation of cathode materials, versatile materials have been chosen, synthesized, or modified to achieve an improvement in power generation of MFCs. The most widely applied cathode materials could be categorized into three classes, namely carbon-base materials, metal-based materials, and biocatalysts. This review summarizes the utilization, development, and the cost of cathode materials applied in MFCs and tries to highlight the effective modification methods of cathode materials which have helped in achieving enhanced power generation of MFCs in recent years.