Biomimetic water-in-oil water/pMDI emulsion as an excellent ecofriendly adhesive for bonding wood-based composites.

In this study, a novel and environmental strategy inspired by mussels is reported for the construction of a high-performance water-in-oil water/pMDI adhesive with strongly adherent catechol groups. It is found that the design of the biomimetic water-in-oil emulsion significantly increases the apparent viscosity and storage stability of the adhesive, which in turn influences the handling and bonding performance in practical application. Additionally, although the biomimetic emulsion design consumes part of active isocyanate groups in the pMDI, the contained catechol can serve as a reactive platform to induce secondary crosslinking interactions with the wood substrate to further improve the mechanical and adhesion performances of the modified pMDI adhesives. Consequently, compared to the pristine pMDI sample, the wet shear strength of the biomimetic water-in-oil water/pMDI adhesive is increased by 129.7 %, exhibiting that the obvious optimization of adhesion and water resistance properties. Overall, our findings provide new insights into exploiting novel and superior wood adhesives, and the constructed high-performance adhesive presents potential applications for sustainable wood products.