Engine Performance of High-Acid Oil-Biodiesel through Supercritical Transesterification.

Relatively cheaper high-acid oil was used to make biodiesel through supercritical methanol transesterification, where high FFA contents in feedstock might conversely enhance the reaction extent. A direct-injection diesel engine and a dynamometer were used to analyze the engine characteristics of the high-acid oil-biodiesel. The experimental results show that the biodiesel made in this study had adequate fuel properties. This present biodiesel from high-acid oil was found to bear a lower heating value and equivalence ratio, with higher exhaust gas temperature, brake-specific fuel consumption (bsfc), and excess air ratio, than super-low sulfur diesel (SLSD). The biodiesel appeared to have larger-sized carbon residue left after the burning process in comparison with that of SLSD. The higher engine speed resulted in higher exhaust gas temperature and equivalence ratio, while lower bsfc, excess air ratio, was observed for the biodiesel. Supercritical methanol transesterification has been successfully proven to convert those low-cost feedstocks to renewable biodiesel products which own competitive engine performance in this study.