Building a Co-Salen-Immobilized Porous Organic Polymer Catalyst for CO2 Cycloaddition.

The CO2-epoxide addition to cyclic carbonate is of great significance but usually requires high temperatures and CO2 pressures. Herein, a spirobifluorene-based porous organic polymer catalyst is designed with a Co-salen complex immobilized on the backbone (ST-CoSalen-POP) to enable CO2 fixation under mild conditions. ST-CoSalen-POP possesses a high Co-loading content (9.35 wt%), a large pore volume, and high CO2 adsorption capacity. This catalyst achieves a 96% yield in the cycloaddition of CO2 with epoxides at 25 °C and 0.1 MPa CO2 pressures. Moreover, ST-CoSalen-POP also offers the advantages of wide adaptability over epoxide substrates and high structural stability for three consecutive cycles. This study presents a novel catalytic approach for promoting CO2 fixation, offering a significant advancement in the efficient synthesis of fine chemicals.