Photo-solid-phase microextraction of selected indoor air pollutants from office buildings. Identification of their photolysis intermediates.

Photo-solid-phase microextraction (photo-SPME) has been employed to study the photolysis of three common indoor air pollutants: coumarin, butylated hydroxytoluene, 2,6-diisopropylnaphthalene. Analytes were first extracted by SPME, and the fibre was subsequently exposed to an irradiation source (i.e. xenon arc or low-pressure mercury lamp) for the selected time (from 2 to 120 min). Analyses of the irradiated fibres were carried out by gas chromatography-mass spectrometry (GC-MS) detection. Photodecay kinetics exhibited a first-order behaviour and their rate constants and half-life times were estimated. Twenty-five photoproducts have been tentatively identified by means of their mass spectra. On the basis of the identified transformation compounds, some photodegradation pathways were proposed. The photoformation-photodecay kinetics of the identified by-products were also monitored by photo-SPME. To the best of our knowledge, photolytic routes for coumarin, butylated hydroxytoluene and 2,6-diisopropylnaphthalene have not been previously investigated.