Dynamical channel coupling in strong-field ionization of CO2.

We present a theoretical study employing the time-dependent density functional theory (TDDFT) to explore the effects of angle-resolved channel coupling in strong field ionization of carbon dioxide (CO2) molecules. Our results reveal significant angular sensitivity of both the channel-resolved ionization probabilities and the effects of laser-induced channel couplings. By applying a linearly polarized two-color field scheme, we demonstrate the ability to significantly modify the strength of the laser-induced coupling, evidenced by the changes in the population distributions among the ionic states induced by the strong-field ionization. Importantly, the two-color field optimally modulates the coupling strength at the alignment angle where ionization of the highest occupied molecular orbital (HOMO) electrons is most efficient. This optimization is attributed to the reduction of the electron shielding effect. Our research provides valuable insights into the coherent manipulation of electron distribution within the cation, paving the way for the precise control of ultrafast electron dynamics during strong-field ionization processes.