Thermally induced structural metamorphosis of ZnO:Rb nanostructures for antibacterial impacts.

In this work, we report on the synthesis of pure and Rb doped ZnO (ZnO:Rb) nanoparticles by a simple combustion technique followed by thermal treatment in an open-air atmosphere. The prepared samples were characterized using UV-vis spectroscopy, X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), photoluminescence, Raman spectroscopy and scanning electron microscopy. The wurtzite hexagonal phase structure of ZnO and a secondary phase of Rb2ZnO2 was observed after doping ZnO with Rb. FTIR and DSC confirmed the functional groups and the thermal stability of the ZnO samples. Field emission scanning electron microscope showed an irregular shaped agglomerated morphology for the ZnO:Rb samples. The chemical states of the undoped and Rb doped samples were identified using X-ray photoelectron spectroscopy for both pure and ZnO:Rb samples. In addition, ZnO:Rb samples exhibit good antimicrobial activities against Bacillus subtilis with a change in antibacterial behaviour as compared to pure ZnO structures indicating their multifunctional applications.