Facile Synthesis of Metal-Organic Layers with High Catalytic Performance toward Detoxification of a Chemical Warfare Agent Simulant.

Two-dimensional (2D) metal-organic layer (MOL) materials are highly desired against chemical warfare agents (CWAs). However, the rapid synthesis of 2DMOLs with open metal sites in a single step is very challenging. Herein, a facile bottom-up method for synthesizing MOLs with microwave assistance is applied to produce Zr/Hf-BTB MOLs, composed of six-connected M6O4(OH)412+ and the tritopic carboxylate ligand 1,3,5-tris(4-carboxyphenyl)benzene (BTB). The synthesis and ligand exchange steps can be combined into a single step to yield MOLs with active open sites directly. The as-synthesized MOLs demonstrate excellent catalytic performance toward the degradation of a CWA simulant. The theoretical calculations confirm that the high catalytic activity is due to the formate groups coordinated to the metal nodes being replaced by hydroxyl groups. The present work not only develops a method for the fast synthesis of 2D MOLs with active open metal sites in a single step but also provides a first demonstration for the application of 2D metal coordination materials in CWA protection.