Copper 1,19-Diaza-21,24-dicarbacorrole: A Corrole Analogue with an N-N Linkage Stabilizes a Ground-State Singlet Organocopper Species.

A copper complex of a heterocorrole analogue with an N-N linkage, 1,19-diaza-21,24-dicarbadibenzocorrole (Cu-5), was successfully synthesized via oxidative metalation-cyclization of a tetrapyrrolic precursor. The N-N linkage in the skeleton of Cu-5, which serves as a mediator of π-electron delocalization, features an 18π aromatic system. The electronic structure of Cu-5 is best described as a ground-state singlet species stabilized by the distinct NNCC coordination core. This finding shows how the ligand's design can be used to modulate the Cu 3 d x 2 - y 2 orbital energy, thereby making such compounds invaluable for copper-based catalytic applications.